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Rubies and sapphires are of both scientific and commercial interest. These gemstones are corundum colored by transition elements within the alumina crystal lattice: Cr3+ yields red in ruby and Fe2+, Fe3+, and Ti4+ ionic interactions color sapphires. A minor ion, V3+ induces slate to purple colors and color change in some sapphires, but its role in coloring rubies remains enigmatic. Trace element and oxygen isotope composition provide genetic signatures for natural corundum and assist geographic typing. Here, we show that V can dominate chromophore contents in Mogok ruby suites. This raises implications for their color quality, enhancement treatments, geographic origin, exploration and exploitation and their comparison with rubies elsewhere. Precise LA-ICP-MS analysis of ruby and sapphire from Mogok placer and in situ deposits reveal that V can exceed 5,000 ppm, giving V/Cr, V/Fe and V/Ti ratios up to 26, 78, and 97 respectively. Such values significantly exceed those found elsewhere suggesting a localized geological control on V-rich ruby distribution. Our results demonstrate that detailed geochemical studies of ruby suites reveal that V is a potential ruby tracer, encourage comparisons of V/Cr-variation between ruby suites and widen the scope for geographic typing and genesis of ruby. This will allow more precise comparison of Asian and other ruby fields and assist confirmation of Mogok sources for rubies in historical and contemporary gems and jewelry. 相似文献
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Niklas Leicher Biagio Giaccio Alison Pereira Sebastien Nomade Lorenzo Monaco Giorgio Mannella Paolo Galli Edoardo Peronance Danilo Mauro Palladino Gianluca Sottili Giovanni Zanchetta Bernd Wagner 《Boreas: An International Journal of Quaternary Research》2023,52(2):240-271
Thirty-two tephra layers were identified in the time-interval 313–366 ka (Marine Isotope Stages 9–10) of the Quaternary lacustrine succession of the Fucino Basin, central Italy. Twenty-seven of these tephra layers yielded suitable geochemical material to explore their volcanic origins. Investigations also included the acquisition of geochemical data of some relevant, chronologically compatible proximal units from Italian volcanoes. The record contains tephra from some well-known eruptions and eruptive sequences of Roman and Roccamonfina volcanoes, such as the Magliano Romano Plinian Fall, the Orvieto–Bagnoregio Ignimbrite, the Lower White Trachytic Tuff and the Brown Leucitic Tuff. In addition, the record documents eruptions currently undescribed in proximal (i.e. near-vent) sections, suggesting a more complex history of the major eruptions of the Colli Albani, Sabatini, Vulsini and Roccamonfina volcanoes between 313 and 366 ka. Six of the investigated tephra layers were directly dated by single-crystal-fusion 40Ar/39Ar dating, providing the basis for a Bayesian age–depth model and a reassessment of the chronologies for both already known and dated eruptive units and for so far undated eruptions. The results provide a significant contribution for improving knowledge on the peri-Tyrrhenian explosive activity as well as for extending the Mediterranean tephrostratigraphical framework, which was previously based on limited proximal and distal archives for that time interval. 相似文献
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Ford AT Fernandes TF Rider SA Read PA Robinson CD Davies IM 《Marine environmental research》2004,58(2-5):169-173
Intersexuality has been found in both males and females of the marine/estuarine amphipod, Echinogammarus marinus, at polluted and reference sites in East Scotland. Polluted sites had significantly more intersex specimens than reference sites, however the cause of intersexuality is unclear. Discriminant analysis of morphometric data showed that normal male specimens from the most polluted site resembled pooled intersex males, suggesting that subtle endocrine disruption (ED) maybe occurring in these otherwise apparently normal males. The main discriminating character was gnathopod size, recognised to be under androgenic gland control. The association of distinctive morphometry with intersexuality may provide a new approach to biomarkers of ED in crustaceans. The opportunities for other novel biomarkers, for example biochemical or behavioural markers, may also be explored through study of intersex animals. 相似文献
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A review of shear wave splitting in the crack-critical crust 总被引：7，自引：0，他引：7
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Intercomparison of Boron Isotope and Concentration Measurements. Part II: Evaluation of Results 总被引：3，自引：1，他引：3
Roberto Gonfiantini Sonia Tonarini Manfred Grning Alessandra Adorni‐Braccesi Assad S. Al‐Ammar Marcus Astner Sebastien Bchler Ramon M. Barnes Randy L. Bassett Alain Cocherie Annette Deyhle Andrea Dini Giorgio Ferrara Jrme Gaillardet Judith Grimm Catherine Guerrot Urs Krhenbühl Graham Layne Damien Lemarchand Anette Meixner D. Jack Northington Maddalena Pennisi Eva Reitznerov Ilia Rodushkin Naoji Sugiura Regina Surberg Sabine Tonn Michael Wiedenbeck Samuel Wunderli Yingkai Xiao Thomas Zack 《Geostandards and Geoanalytical Research》2003,27(1):41-57
The Istituto di Geoscienze e Georisorse (IGG), on behalf and with the support of the International Atomic Energy Agency (IAEA), prepared eight geological materials (three natural waters and five rocks and minerals), intended for a blind interlaboratory comparison of measurements of boron isotopic composition and concentration. The materials were distributed to twenty seven laboratories - virtually all those performing geochemical boron isotope analyses in the world -which agreed to participate in the intercomparison exercise. Only fifteen laboratories, however, ultimately submitted the isotopic and/or concentration results they obtained on the intercomparison materials. The results demonstrate that interlaboratory reproducibility is not well reflected by the precision values reported by the individual laboratories and this observation holds true for both boron concentration and isotopic composition. The reasons for the discrepancies include fractionations due to the chemical matrix of materials, relative shift of the zero position on the δ11 B scale and a lack of well characterized materials for calibrating absolute boron content measurements. The intercomparison materials are now available at the IAEA (solid materials) and IGG (waters) for future distribution. 相似文献
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A note on 10Be‐derived mean erosion rates in catchments with heterogeneous lithology: examples from the western Central Andes 
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下载免费PDF全文 Sebastien Carretier Vincent Regard Riccardo Vassallo Joseph Martinod Frederic Christophoul Eric Gayer Laurence Audin Christelle Lagane 《地球表面变化过程与地形》2015,40(13):1719-1729
Millennial catchment–mean erosion rates derived from terrestrial cosmogenic nuclides are generally based on the assumption that the lithologies of the parent rock each contain the same proportion of quartz. This is not always true for large catchments, in particular at the edge of mountainous plateaus where quartz‐rich basement rocks may adjoin sedimentary or volcano‐sedimentary rocks with low quartz content. The western Central Andes is an example of this type of situation. Different quartz contents may be taken into account by weighting the TCN production rates in the catchment. We recall the underlying theory and show that weighting the TCN production rate may also lead to bias in the case of a spatial correlation between erosion rate and lithology. We illustrate the difference between weighted and unweighted erosion rates for seven catchments (16 samples) in southern Peru and northern Chile and show variations up to a factor of 2 between both approaches. In this dataset, calculated erosion rates considering only granitoid outcrops are better correlated with catchment mean slopes than those obtained without taking into account the geological heterogeneity of the drained watershed. This dataset analysis demonstrates that weighting erosion rates by relative proportions of quartz is necessary to evaluate the uncertainties for calculated catchment–mean erosion rates and may reveal the correlation with geomorphic parameters. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
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Dario Dello Iacono Aldo Zollo Maurizio Vassallo Tiziana Vanorio Sebastien Judenherc 《Bulletin of Volcanology》2009,71(3):275-284
In September 2001, an extensive active-seismic investigation (Serapis experiment) was carried out in the Gulfs of Naples and
Pozzuoli, with the aim of investigating and reconstructing the shallow crustal structure of the Campi Flegrei caldera, and
possibly identifying its feeding system at depth. The present study provides a joint analysis of the very shallow seismic
reflection data and tomographic images based on the Serapis dataset. This is achieved by reflection seismic sections obtained
by the 3D data gathering and through refined P-velocity images of the shallowest layer of Pozzuoli Gulf (z < 1,000 m). From the refined Vp model, the overall picture of the velocity distribution confirms the presence of a complex
arc-shaped anomaly that borders the bay offshore. The deeper part of the anomaly (beneath 700 m, with Vp > 3,500 m/s) correlates
with units made up of agglomerate tuffs and interbedded lava, which form the southern edge of the caldera, which was probably
formed following the two large ignimbritic eruptions that marked the evolutionary history of the area under study. The upper
part of the anomaly that tends to split into two parallel arcs is correlated with dikes, volcanic mounds and hydrothermal
alteration zones noted in previous shallow reflection seismic analyses. The depth of the transition between the upper and
lower parts of the anomaly is characterized by an abrupt Vp increase on the one-dimensional (1D) profiles extracted from the
3D tomographic model and by the presence of a strong reflector located at about 0.6/0.7 s Two Way Time (TWT) on Common Mid
Point gathers. The move-out velocity analysis and stack of the P–P and P–S reflections at the layer bottom allowed to estimate
relatively high Vp/Vs values (3.7 ± 0.9). This hypothesis has been tested by a theoretical rock physical modeling of the Vp/Vs
ratio as a function of porosity suggesting that the shallow layer is likely formed by incoherent, water saturated, volcanic
and marine sediments that filled Pozzuoli Bay during the post-caldera activity. 相似文献